COPPER AND BRASS SALES INC -- C22000 COMMERCIAL BRONZE ======================================================= MSDS Safety Information ======================================================= FSC: 3439 MSDS Date: 02/01/1996 MSDS Num: BZWPK LIIN: 00F049809 Product ID: C22000 COMMERCIAL BRONZE MFN: 01 Responsible Party Cage: COPPE Name: COPPER AND BRASS SALES INC Address: 17401 TEN MILE RD City: EASTPOINTE MI 48021-1256 Info Phone Number: 215-586-1800/810-775-7710 Emergency Phone Number: 215-586-1800/810-775-7710 Review Ind: Y Published: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: COPPE Assigned Ind: Y Name: COPPER AND BRASS SALES INC Address: 17401 TEN MILE RD City: EAST DETROIT MI 48021 ======================================================= Contractor Summary ======================================================= Cage: COPPE Name: COPPER AND BRASS SALES INC Address: 17401 TEN MILE RD City: EAST DETROIT MI 48021 Phone: 313-775-7710 Cage: 93932 Name: COPPER CHEMICALS CO/ELKHART, IN 46514 Address: UNKNOWN City: UNKNOWN NK 00000 Phone: UNKNOWN ======================================================= Ingredients ======================================================= Cas: 7440-50-8 RTECS #: GL5325000 Name: COPPER (DUST & MIST), BRONZE POWDER *96-2* % Wt: 90 Other REC Limits: 1 MG(CU)/M3 (DUST) OSHA PEL: 0.1 MG(CU)/M3 (FUME) ACGIH TLV: 0.2 MG/M3 (FUME) EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 1314-13-2 RTECS #: ZH4810000 Name: ZINC OXIDE *96-2* % Wt: 10 OSHA PEL: 5 MG/CUM ACGIH TLV: 5 MG/CUM FUME ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: COPPER-INHALATION: FUMES MAY CAUSE METAL FUME FEVER. SKIN: DERMATITIS, KERATINIZATION OF THE HANDS & THE SOLES OF THE FEET. COPPER DUST & FUME CAUSES IRRITATION OF THE UPPER RESPIRATORY TRACT. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: COPPER-FLU-LIKE SYMPTOMS, SKIN & HAIR DISCOLORATION, METALLIC TASTE IN THE MOUTH, NAUSEA. First Aid: EYES: FLUSH W/RUNNING WATER. SKIN: VACUUM OFF EXCESS DUST. WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: LARGE: REMOVE BY VACUUMING/WET SWEEPING TO PREVENT HEAVY CONCENTRATION OF AIRBORNE DUST. IF LIQUIDS CONTAINING SOLUBILIZED METAL ARE SPILLED EVACUATE AREA. ABSORB BY MEANS OF VERMICULITE, DRY SAND/SIMILAR MATERIAL. (SEE SUPP) Waste Disposal Methods: DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: STORE AWAY FROM INCOMPATIBLE MATERIALS & KEEP DUST FROM IGNITION SOURCES. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: USE SPECIAL MIXTURES OF DRY CHEMICAL/SAND. Fire Fighting Procedures: WEAR NIOSH/MSHA SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard: SOLID MASSIVE FORM ISN'T COMBUSTIBLE. MOLTEN METAL MAY REACT VIOLENTLY W/WATER. ======================================================= Control Measures ======================================================= Respiratory Protection: IF EXPOSURE ABOVE THE PEL/TLV, WEAR NIOSH/MSHA APPROVED RESPIRATOR. Ventilation: LOCAL EXHAUST VENTILATION. Protective Gloves: REQUIRED Eye Protection: SAFETY GLASSES W/SIDE SHIELDS Other Protective Equipment: FACE SHIELDS, SPECIALLY TINTED GLASS. Supplemental Safety and Health: SPILLS CONT'D: CLEANUP PERSONNEL SHOULD WEAR RESPIRATORS & PROTECTIVE CLOTHING. VENTILATE AREA. ======================================================= Physical/Chemical Properties ======================================================= M.P/F.P Text: 1290-2260F Spec Gravity: 7.45-9 Solubility in Water: INSOLUBLE Appearance and Odor: SILVER/YELLOW TO RED COLOR SOLID W/NO ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: WATER, HEAT, FLAMES, CHEMICAL REACTIONS. Materials To Avoid: OXIDIZERS, ACIDS, BASES Hazardous Decomposition Products: METAL FUME. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: C22000 COMMERCIAL BRONZE Cage: COPPE Assigned IND: Y Company Name: COPPER AND BRASS SALES INC Street: 17401 TEN MILE RD City: EAST DETROIT MI Zipcode: 48021 Health Emergency Phone: 215-586-1800/810-775-7710 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: COPPER-INHALATION: FUMES MAY CAUSE METAL FUME FEVER. SKIN: DERMATITIS, KERATINIZATION OF THE HANDS & THE SOLES OF THE FEET. COPPER DUST & FUME CAUSES IRRITATION OF THE UPPER RESPIRATORY TRACT. COPPER-FLU-LIKE SYMPTOMS, SKIN & HAIR DISCOLORATION, METALLIC TASTE IN THE MOUTH, NAUSEA. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.