VAN WATERS & ROGERS INC -- HYDROGEN PEROXIDE (20 TO 60%) ======================================================= MSDS Safety Information ======================================================= FSC: 6810 MSDS Date: 04/03/1998 MSDS Num: CHTWL LIIN: 00N089289 Product ID: HYDROGEN PEROXIDE (20 TO 60%) MFN: 01 Responsible Party Cage: DO735 Name: VAN WATERS & ROGERS INC Address: 6100 CARILLON POINT City: KIRKLAND WA 98033-7357 Info Phone Number: 425-889-3617 Emergency Phone Number: 800-424-9300 (CHEMTREC) Published: Y ======================================================= Contractor Summary ======================================================= Cage: DO735 Name: VAN WATERS & ROGERS SUB OF UNIVAR Address: 6100 CARILLON POINT City: KIRKLAND WA 98033 Phone: 425-889-3400 Cage: 0STM5 Name: VAN WATERS AND ROGERS INC Address: 6100 CARILLON POINT City: KIRKLAND WA 98033-7357 Phone: 425-889-3400/425-889-3617 ======================================================= Ingredients ======================================================= Cas: 7722-84-1 RTECS #: MX0900000 Name: HYDROGEN PEROXIDE (SARA 302) % Wt: 20-60 OSHA PEL: 1 PPM ACGIH TLV: 1 PPM ------------------------------ Cas: 7732-18-5 RTECS #: ZC0110000 Name: WATER % Wt: 40-80 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Name: EXPLO HAZ: MAY CAUSE FIRE. EFTS MAY BE DELAYED. CONT W/ORG LIQS/VAPS MAY CAUSE IMMED FIRE/EXPLO, ESP IF HEATED. ----------------------------- Name: ING 3: UNDER CERTAIN CNDTNS, DETONATION MAY BE DELAYED. OXYGEN RELEASE FROM HYDROGEN PEROXIDE MAY FORCE ORG OR ----------------------------- Name: ING 4: HYDROGEN VAPORS INTO EXPLOSION RANGE. FOLLOW APPROP NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) CODES. ----------------------------- Name: HAZ DECOMP PROD: PRESS. MAY REACT DANGEROUSLY W/RUST, DUST, IRON, COPPER, HEAVY METALS/THEIR SALTS (SUCH AS ----------------------------- Name: ING 6: MERCURIC OXIDE/CHLORIDE), ALKALIES, & WITH ORGANIC MATERIALS (ESPECIALLY VINYL MONOMERS). ----------------------------- Name: EFTS OF OVEREXP: DISCOMFORT, DFCLTY BRTHG/SHORTNESS OF BREATH; OR FATALITY FROM GROSS OVEREXP. INGEST MAY CAUSE ----------------------------- Name: ING 8: IRRIT OF GI TRACT W/UPPER ABDOM PAIN, "HEARTBURN", NAUS, VOMIT, & DIARR. "COFFEE GROUNDS" VOMITUS & BLACK ----------------------------- Name: ING 9: TARRY STOOLS MAY OCCUR AS RSLT OF GI TRACT BLEEDING. ADDNL EFTS FROM OVEREXP INCL RED BLOOD CELL DESTRUCT ----------------------------- Name: ING 10: OR GAS EMBOLISM. WHEN USED AS COLONIC LAVAGE, HYDROGEN PEROXIDE HAS CAUSED GAS EMBOLISM & GANGRENE OF ----------------------------- Name: ING 11: INTESTINE AT CONCS DOWN TO 0.75%. GROSS OVEREXP BY INGEST MAY BE FATAL. FOR TOXICOLOGICAL INFO CONT NEHC (FP N). ----------------------------- Name: FIRST AID PROC: BY MOUTH TO AN UNCON PERS. CALL MD. NOTES TO MD: IF SWALLOWED, LGE AMTS OF OXYGEN MAY BE ----------------------------- Name: ING 13: RELEASED QUICKLY. DISTENSION OF STOM/ESOPHAGUS MAY BE INJURIOUS. INSERTION OF GASTRIC TUBE MAY BE ADVISABLE. ----------------------------- Name: SPILL PROC: METABISULFITE/SODIUM SULFITE (1.9 LBS SO*2 EQUIVALENT PER LB OF PEROXIDE) AFTER DILUTING TO 5-10% ----------------------------- Name: ING 15: PEROXIDE. REPORTABLE QTY FOR >52% HYDROGEN PEROXIDE IS 1 LB. IF HYDROGEN PEROXIDE (20-60%) IS SPILLED & ----------------------------- Name: ING 16: NOT RECOVERED, OR IS RECOVERED AS WASTE FOR TREATMENT OR DISPOSAL, THE CERCLA REPORTABLE QUANTITY IS 100 LBS. ----------------------------- Name: WASTE DISP METH: REGULATED HAZ WASTE UPON DISPOSAL DUE TO THE OXIDIZING CHARACTETISTICS UNDER IGNITABILITY CATEGORY. ----------------------------- Name: OTHER PREC: IMPURITIES, CONTAMINANTS, TEMPS, ETC. NEVER USE PRESS TO EMPTY DRUMS. STORE IN PROPERLY VENTED CONTR ----------------------------- Name: ING 19: OR IN APPRVD BULK STOR FACILITIES. DO NOT BLOCK VENT. DO NOT STORE ON WOODEN PELLETS/WHERE CONT WITH ----------------------------- Name: ING 20: INCOMPATIBLE MATLS COULD OCCUR, EVEN W/SPILL. HAVE WATER SOURCE AVAIL FOR DILUTING. DO NOT ADD ANY OTHER ----------------------------- Name: ING 21: PROD TO CONTR. NEVER RETURN USED/UNUSED PEROXIDE TO CONTR, INSTEAD DILUTE W/PLENTY OF WATER & DISCARD. ----------------------------- Name: ING 22: RINSE EMPTY CONTAINERS THOROUGHLY WITH CLEAN WATER BEFORE DISCARDING. ----------------------------- Name: OTHER PROT EQUIP: SUIT W/BRTHG AIR SUPPLY. MATLS SUCH AS NATRL RUBB, NATRL RUBB PLUS NEOPRENE, NITRILE/PVC ----------------------------- Name: ING 24: AFFORD ADEQ PROT. ADEQ PERS PROT IS ESSENTIAL FOR ALL INDUSTRIAL CONCENTRATIONS. SKIN CREAMS SHOULD NOT BE USED. ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50(ORAL RAT): 1232 MG/KG (35% H*2O*2). Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: SKIN: CONT W/AQUEOUS SOLNS OF <50% MAY CAUSE IRRIT W/DISCOMFORT/RASH. HIGHER/PRLNG EXPOS MAY RSLT IN SKIN BURNS/ULCERATION. EVIDENCE SUGGESTS THAT SKIN PERMEATION CAN OCCUR IN AMTS CAPABLE OF PRODUCING SYSTEMIC TOXICITY. EFTS OF EYE CONT W/AQUEOUS SOLNS OF <5% MAY INCL EYE IRRIT W/DISCOMFORT, (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: TEARING/BLURRING OF VISION. HIGHER/PRLNG EXPOS MAY RSLT IN EYE CORR W/CORNEAL/CONJ ULCERATION. CONT W/AQUEOUS CONCS OF >10% MAY RSLT IN EYE CORR W/CORNEAL/CONJ ULCERATION WHICH CAN LEAD TO BLINDNESS. INHAL MAY CAUSE NAUS, HDCH/WEA K. HIGHER INHAL EXPOS MAY LEAD TO TEMPORARY LUNG IRRIT EFTS W/COUGH, Medical Cond Aggravated By Exposure: INDIVIDUALS WITH PREEXISTING DISEASES OF THE SKIN, EYES, OR LUNGS MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. First Aid: INHAL: IMMED REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL MD. SKIN: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS WHILE REMOVING CONTAM CLTHG & SHOES. CALL MD. WASH CONTAM CLTHG & SHOES PROMPT LY & THORO. EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. CALL MD. INGEST: DO NOT INDUCE VOMIT. GIVE LGE QTYS OF WATER. NEVER GIVE ANYTHING ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: USE APPROP PERS PROT EQUIP DURING CLEAN-UP. COMPLY W/FED, STATE, & LOC REGS ON REPORTING RELEASES OF WASTES. FLOOD AREA W/WATER & DRAIN TO APPRVD CHEM SEWER/WASTEWATER TREATMENT SYS, INCL MUNICIPAL SEWERS IF APPRVD. MAY BE DESTROYED W/SODIU M Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: COMPLY W/FED, STATE, & LOC REGS. IF APPRVD, MAY BE DILUTED & DRAINED TO MUNICIPAL SEWER/WASTE TREATMENT PLANT. MAY BE DILUTED & DRAINED THRU SCRAP METAL PIT (IRON, COPPER, ETC) RO REDUCE PEROXIDE CONC. HYDROGEN PEROXIDE MAY BE AN RCRA Handling And Storage Precautions: DO NOT GET IN EYES. DO NOT TASTE/SWALLOW. AVOID CONT W/SKIN & CLTHG. AVOID CONT W/FLAM/COMBUST MATLS. AVOID CONTAM FROM ANY SOURCE. Other Precautions: USE EXTREME CARE WHEN ATTEMPTING ANY RXNS BECAUSE OFFIRE & EXPLO POTENTIAL (IMMED/DELAYED). CONDUCT ALL INITIAL EXPTS ON SMLSCALE & PROTECT PERS W/ADEQ SHIELDING AS RXNS ARE UNPREDICTABLE & MAY BEDELAYED, & MAY BE AFFECTED BY ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: USE ONLY WATER. Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). FLOOD WITH WATER. COOL TANK/CONTAINER WITH WATER SPRAY. Unusual Fire/Explosion Hazard: WILL NOT BURN, BUT DECOMP, WHICH MAY BE CAUSED BY HEAT/CONTAM WILL CAUSE RELEASE OXYGEN WHICH WILL INTENSIFY FIRE. STRONG OXIDIZER. CONT W/CLTHG/COMBUSTS ======================================================= Control Measures ======================================================= Respiratory Protection: WHERE THERE IS POTENTIAL FOR AIRBORNE EXPOSURE IN EXCESS OF APPLICABLE LIMITS, WEAR NIOSH APPROVED RESPIRATORY PROTECTION. Ventilation: USE SUFFICIENT VENTILATION TO KEEP EMPLOYEE EXPOSURE BELOW RECOMMENDED EXPOSURE LIMITS. Protective Gloves: IMPERVIOUS GLOVES. Eye Protection: ANSI APPRVD CHEM WORKERS GOGG (SUP DAT) Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER (FP N). APRON, PANTS, JACKET, HOOD, & BOOTS/TOTALLY ENCAPSULATED CHEM Work Hygienic Practices: WASH THORO AFTER HNDLG. DO NOT WEAR LEATHER GLOVES/SHOES(UPPERS/SOLES)/COTTON CLTHG; THEY CAN IGNITE ON CONT W/PEROXIDE. Supplemental Safety and Health: BP: 20%: 217F/103C; 35%: 226/108C; 50%: 237F/114C; 60%: 246F/119C. SPEC GRAV: 20%: 1.07; 35%: 1.13; 50%: 1.19; 60%: 1.24. VP (@ 77F/25C): 20%: 20.6; 35%: 17.4; 50%: 13.5; 60%: 10.7. MP: 20%: 5.7F/-14.6C; 35%: -27.4F/-33.0C; 50%: -62.0F/-52. 2C; 60%: -67.9F/-55.5C. EYE PROT: & FULL LENGTH FACESHIELD (FP N). ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: SUP DAT M.P/F.P Text: SUP DAT Vapor Pres: SUP DAT Spec Gravity: SUP DAT Evaporation Rate & Reference: >1 Solubility in Water: 100 WT% Appearance and Odor: COLORLESS WITH SLIGHTLY PUNGENT, IRRITATING ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: NO Stability Condition To Avoid: HEAT OR CONTAMINATION. LIBERATION OF OXYGEN GAS MAY RESULT IN DANGEROUS PRESSURES. Materials To Avoid: MOST FLAM/COMBUSTS, CYANIDES, NITRIC ACID, POTASSIUM PERMANGANATE, OXIDIZING/REDUCING AGENTS. MIXT W/ORGS & SOME ACIDS. Hazardous Decomposition Products: CONTAM/HEAT MAY CAUSE SELF-ACCELERATING EXOTHERMIC DECOMP W/OXYGEN GAS & STEAM RELEASE THAT CAN CAUSE DANGEROUS Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: HYDROGEN PEROXIDE (20 TO 60%) Cage: DO735 Assigned IND: Y Company Name: VAN WATERS & ROGERS SUB OF UNIVAR Street: 6100 CARILLON POINT City: KIRKLAND WA Zipcode: 98033 Health Emergency Phone: 800-424-9300 (CHEMTREC) Label Required IND: Y Date Of Label Review: 09/03/1998 Status Code: C Label Date: 09/03/1998 Origination Eye Protection IND: YES Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Slight Reactivity Hazard: Slight Hazard And Precautions: ACUTE: SKIN: CONT W/AQUEOUS SOLUTIONS OF <50% MAY CAUSE IRRIT W/DISCOMFORT/RASH. HIGHER/PROLONGED EXPOS MAY RESULT IN SKIN BURNS/ULCERATION. EVIDENCE SUGGESTS THAT SKIN PERMEATION CAN OCCUR IN AMOUNTS CAPABLE OF PRODUCING SYSTEMIC TOXICITY. EFFECTS OF EYE CONT W/AQUEOUS SOLUTIONS OF <5% MAY INCLUDE EYE IRRIT W/DISCOMFORT, TEARING/BLURRING. MAY RESULT IN EYE CORROSION W/CORNEAL OR CONJUNCTIVAL ULCERATION & MAY LEAD TO BLINDNESS. INHAL: MAY CAUSE NAUS, HEADACHE, WEAKNESS, LUNG IRRIT, COUGH, DIFFICULTY BREATHING, & FATALITY. INGEST: MAY CAUSE GI IRRIT, ABDOMINAL PAIN, NAUS, VOMIT & DIARRHEA. MAY BE FATAL. CHRONIC: NONE LISTED BY MANUFACTURER. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.