Lateral or vertical — that is the question!
Which structures are they going to form and how will they be oriented? Would mixing allow a finetuning of the thin film structures for special applications, e.g. in nanolithography, without resorting to substrate prestructuring? The team investigated blends of long and short PS-b-P2VP (polystyrene-b-Poly(2-vinylpyridine) with a length ratio of short to long chains of 1:6.9. Each of these polymers microphase separate into lamellar structures by itself, albeit with different period. Blends should feature coexisting domains of thin and thick AB lamellae [2,3].