Breakdown of the Small-Polaron Hopping Model in Higher-Order Spinels
Spinel oxides are ceramics with exciting electronic and electrochemical properties. Spinels have important roles in devices such as batteries and fuel cells, but there are limits to their integration because of their low electronic conductivity. The conventional model to describe charge transport in oxides was developed six decades ago and had not been tested on complex materials such as ternary spinel oxides, and, as a result, impeding the ability to understand and improve the conductivity of oxides.